金属钛制备工艺研究进展  

Research Progress of Production of Metallic Titanium

作　　者：曹大力[1] 王吉坤[2] 邱竹贤[1] 石忠宁[1] 王兆文[1] 郭思辰[3] 

机构地区：[1]东北大学材冶学院 [2]云南冶金集团科技部,云南昆明650016 [3]沈阳化工学院材料科学与工程学院,辽宁沈阳110141

出　　处：《钛工业进展》2008年第4期9-13,共5页Titanium Industry Progress

基　　金：国家"973"项目(G199906403);(G199906503);国家自然科学重点基金项目(50334030);辽宁博士启动基金项目(20041010)

摘　　要：本文介绍了热还原法制备金属钛的工艺,包括Kroll法、镁还原低价卤化物、PRP法及Hunter法及电解法,包括电解TiCl4法、FFC剑桥工艺、EMR/MSE等,分析了各种方法的机理及特点。并且认为以TiCl4为原料制备钛工艺降低成本的空间很小;如能生产出低成本的TiCl2,钛成本高的问题将很快得以解决;从熔盐中直接电解TiO2制备金属钛,是低成本金属钛制备新工艺的发展方向。Titanium production processes of thermo-reduction including Kroll process, subhalide reduction process, PRP process, Hunter process, and of molten salt electrolysis processes including electrolysis TiCl4 process, FFC Cambridge process, EMR/MSE process are briefly introduced. The mechanisms and characteristics of various processes for producing metallic titanium are summarized and analyzed. We think it is difficult to reduce the titanium price if using TiCl4 as raw materials; however it is easy to reduce the price using TiCl2 as raw materials if TiCl2 can be made at low cost. It is a new trend to reduce the cost by direct electrochemical reduction of titanium dioxide to titanium in molten salts.

关 键 词：金属钛 热还原 电解 TICL4 TiCl2 TIO2 

分 类 号：TF823[冶金工程—有色金属冶金] TG146.23[一般工业技术—材料科学与工程]