Highly efficient oxidation of alcohols using Oxone~ as oxidant catalyzed by ruthenium complex under mild reaction conditions  

作　　者：Zi Qiang Lei Jian Qiang Wang Peng Hua Yan 

机构地区：[1]Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

出　　处：《Chinese Chemical Letters》2008年第9期1031-1034,共4页中国化学快报（英文版）

基　　金：National Natural Science Foundation of China(No.20774074 and 20674063);Specialized Research Fund for the Doctoral Program of Higher Education(No.20050736001).

摘　　要：Aromatic and alkyl alcohols were oxidized to the corresponding aldehydes or ketones at room temperature with high conversion and selectivity using Oxone （2KHSOs-KHSO4.K2SO4） as oxidant catalyzed by ruthenium complex Quin-Ru-Quin （where Quin = 8-hydroxyquinoline）. The reaction time is very short and the preparation of complex is simple.Aromatic and alkyl alcohols were oxidized to the corresponding aldehydes or ketones at room temperature with high conversion and selectivity using Oxone （2KHSOs-KHSO4.K2SO4） as oxidant catalyzed by ruthenium complex Quin-Ru-Quin （where Quin = 8-hydroxyquinoline）. The reaction time is very short and the preparation of complex is simple.

关 键 词：Oxidation of alcohols OXONE Ruthenium complex 

分 类 号：O643.36[理学—物理化学]