双核大环配合物及其仿生特性  

DINUCLEAR MACROCYCLIC COMPLEXES AND THEIR BIOMIMETIC PROPERTIES

作　　者：刘劲刚[1] 谢复新[1] 赵亮[1] 倪诗圣[1] 

机构地区：[1]安徽大学化学系

出　　处：《化学研究与应用》1997年第5期435-442,共8页Chemical Research and Application

摘　　要：双核大环配合物在模拟金属蛋白活化中心，键合与活化小分子及作为双功能催化剂方面具有广阔应用前景。本文就西夫碱型、串连型、具有“软”、“硬”空腔的单大环、双大环及大多环双核配体及其配合物的性质和它们在仿生方面的研究进展进行综述报道。Dinuclear macrocyclic complexes can be investigated as model compounds.Promising properties are expected for their application to mimic the active centre of metalloprotein,to bind and activate small molecules and to be used as bifunctional catalyst.Several types of macrocycles and their dinuclear complexes,according to their biomimetic feature are reviewed.

关 键 词：大环配体 双核大环配合物 仿生 双核配合物 

分 类 号：O641.4[理学—物理化学]