非离子表面活性剂Brij35胶束体系中α-溴代萘的室温燐光  

Room Temperature Phosphorescence of α-Bromonaphthalene in Non-ionic Surfactant Brij35 Micellar System

作　　者：魏雁声 杨欣[1] 晋卫军[1] 张淑珍 陈容亮 刘长松[1] 

机构地区：[1]山西大学化学系,太原030006

出　　处：《分析化学》1997年第11期1259-1263,共5页Chinese Journal of Analytical Chemistry

基　　金：国家自然科学基金!(No29375203);山西省教委基金

摘　　要：建立了非离子表面活性剂Ｂｒｉｊ３５胶束介质中α－溴代萘的燐光分析法，并与十二烷基 硫酸钠ＳＬＳ体系作了比较。方法特点如下：α－溴代萘在低浓度的Ｂｒｉｊ３５胶束溶液中即产生 ＲＴＰ发射，具有良好的分析特性。甲醇、乙醇等的加入，体系不会使燐光达到稳定的时间增长，测量操作简便。ＴｌＮＯ３的存在使背景降低，精密度提高。Ｂｒｉｊ３５体系比 ＳＬＳ体系具有较大 的粘度，较小的丙酮猝灭影响。The room temperature phosphorescence (RTP) of a-bromonaphthalene in non- ionic surfactant Brij 35 micelle has been studied and compared with that in SLS system. The results showed that a-bromonaphthalene has excellent analytical characteristics even in low concentration of Brij 35 and the RTP of a-bromonaphthalene is free from the influence of the presence of methanol and ethanol, which leads to the increase of chemical deoxygenation time in the SLS system. The addition of TlNO3 decreases the background and improves the precision. The Brij35 system possesses larger viscosity and lower quenching effect from ace- tone than those in SLS system.

关 键 词：表面活性剂 室温Ling光 Α-溴代萘 α-溴萘 

分 类 号：O625.23[理学—有机化学] O647.2[理学—化学]