乙酰二茂铁缩肼基硫代甲酸苄酯的制备、晶体结构及光谱研究  

Study on the synthesis,cystal structure and spectra of S-benzyl-N,N'-(ferrocenyl-1-methyl-metylidene)-dithiocarbazate

作　　者：曹运珠[1] 韩晶[1] 毋丹[1] 王小静[1] 王玥[1] 葛茂发[2] 邢永恒[1] 

机构地区：[1]辽宁师范大学化学化工学院,辽宁大连116029 [2]中国科学院化学研究所,北京100080

出　　处：《化学研究与应用》2008年第9期1185-1189,共5页Chemical Research and Application

基　　金：国家自然科学基金(20771051)资助项目;辽宁省教育基金(05L212)资助项目

摘　　要：A mixing solution of the prepared acetylferrocene and S-benzyl-N-Dithiocarbazate in ethanol with 1∶1 mole ratio is kept on reflux in water bath.Then the goal compound S-benzyl-N,N’-(ferrocenyl-1-methyl-metylidene)-Dithiocarbazate(HLSB)is obtained.The structure of title amplex is characterized by IR spectra,UV spectra.A Schiff base compound with phenyl-and ester alkyl is synthesized.The compound consist of one-dimensional chain that is linked together by a kind of weak H-bonding(N1-H1B——S1A(-x+1,y+1/2,-z+1/2)).A mixing solution of the prepared acetylferrocene and S-benzyl-N-Dithiocarbazate in ethanol with 1：1 mole ratio is kept on reflux in water bath. Then the goal compound S-benzyl-N, N＇ - （ ferrocenyl-1 -methyl-metylidene ） -Dithiocarbazate （ HLSB ） is obtained. The structure of title amplex is characterized by IR spectra, UV spectra. A Schitf base compound with phenyl- and ester alkyl is synthesized. The compound consist of one-dimensional chain that is linked together by a kind of weak H-bonding （ N1- H1B---S1A （-x＋1, y＋1/2, -z＋1/2））.

关 键 词：乙酰基二茂铁 合成 晶体结构 光谱 

分 类 号：O641.4[理学—物理化学]