酯交换合成碳酸二苯酯催化剂的研究进展  

The progress of catalysts in synthesis of diphenyl carbonate by transesterification of dimethyl carbonate and phenol

作　　者：赵强[1] 孟双明[1] 王俊丽[1] 郭永[1] 樊月琴[1] 李忠[2] 

机构地区：[1]山西大同大学化学与化工学院,山西大同037009 [2]太原理工大学煤科学与技术教育部和山西省重点实验室,山西太原030024

出　　处：《化工科技》2008年第4期51-55,共5页Science & Technology in Chemical Industry

基　　金：国家重点基础研究发展计划(2005CB221204);国家自然科学基金资助项目(20576085)

摘　　要：对近年来碳酸二甲酯和苯酚酯交换合成碳酸二苯酯的催化剂体系进行了较为系统的概述,包括均相催化剂体系(碱或碱金属化合物、Lewis酸、锡和钛的有机化合物等)和多相催化剂体系(各种负载型、金属氧化物、水滑石等),认为开发有机锡、有机钛配合物催化剂以及将其固载化是碳酸二甲酯与苯酚酯交换反应合成碳酸二苯酯催化剂研究的重要方向。The systems of catalysts developed recently of transesterification between dimethyl carbonate and phenol to diphenyl carbonate （DPC） were reviewed, including homogeneous catalysts （alkali or alkali metal compounds, Lewis acids, organo-tin compounds, organo-titanium compounds, etc. ） and heterogeneous catalysts （the catalysts supported on zeolites, SiO2, active carbon or others, the composite of metal oxide, the organic anion-pillared hydrotalcites, etc. ）. The development and immobilization of tin and titanium compounds were thought as important research trends for transesterification of dimethyl carbonate and phenol to diphenyl carbonate.

关 键 词：碳酸二甲酯 碳酸二苯酯 催化剂 进展 

分 类 号：TQ225.52[化学工程—有机化工]