2, 6-二氯苯甲酸桥联的双核锰配合物的水热合成与晶体结构(英文)  

Hydrothermal Synthesis and Crystal Structure of a Manganese(Ⅱ) Compound Bridged by 2,6-dichlorobenzoic Acid

作　　者：张春华[1] 唐斯萍[1] 陈满生[1] 邝代治[1] 邓奕芳[1] 

机构地区：[1]衡阳师范学院化学与材料科学系,衡阳421008

出　　处：《无机化学学报》2008年第9期1519-1522,共4页Chinese Journal of Inorganic Chemistry

基　　金：湖南省自然科学基金资助项目(No05JJ30016);湖南省教育厅重点项目(No07A013);湖南省高校"十一五"重点建设学科资助项目

摘　　要：A dinuclear manganese(Ⅱ) complex, [Mn2(L1)2(phen)4]·(ClO4)2 (1), has been synthesized and structurally characterized (HL1=2,6-dichlorobenzoic acid, phen=1,10-phenanthroline). It crystallizes in triclinic system, space group P1 with a=1.112 3(4) nm, b=1.378 2(4) nm, c=2.085 7(3) nm, α=93.768(2)°, β=90.606(10)°, γ=95.606(3)°, V=3.174 8(15) nm3, Z=2, C62H38Cl6Mn2N8O12, Mr=1 409.58, Dc=1.475 g·cm-3, μ=0.718 mm-1, F(000)=1 428, R=0.064 3, wR=0.138 3. In the crystal the manganese atom is six-coordinated by two oxygen atoms from two different 2,6-dichlorobenzolate molecules and four nitrogen atoms from two 1,10-phenanthroline molecules, completing an octahedral geometry. CCDC: 692296.A dinuclear manganese（Ⅱ） complex, [Mn2（L^1）2（phen）4]·（ClO4）2 （1）, has been synthesized and structurally characterized （HL^1=2,6-dichlorobenzoic acid, phen=1,10-phenanthroline）. It crystallizes in triclinic system, space group P1^- with a=1.112 3（4） nm, b=1.378 2（4） nm, c=2.085 7（3） nm, α=93.768（2）°, β=90.606（10）°, γ=95.606（3）°, V=3.174 8（15） nm^3, Z=2, C62H38Cl6Mn2N8O12, Mr=1 409.58, Dc=1.475 g ·cm^-3,μ=0.718 mm^-1, F（000）=1 428, R= 0.064 3, wR=0. 138 3. In the crystal the manganese atom is six-coordinated by two oxygen atoms from two different 2,6-dichlorobenzolate molecules and four nitrogen atoms from two 1,10-phenanthroline molecules, completing an octahedral geometry. CCDC： 692296.

关 键 词：锰配合物 晶体结构 2 6-二氯苯甲酸 水热合成 

分 类 号：O614.711[理学—无机化学]