1,4-二噻英-二苯基四氮杂卟啉铁及其氯代衍生物的合成、表征及HPLC检测分析  

Synthesis and Characterization of Assymmetric Iron(Ⅱ) 1,4-Dithiin-Phenyl-Porphyrazine and Chloridized Derivatives

作　　者：廖晖[1] 王浩[2] 陈连清[2] 孙杰[2] 邓克俭[2] 

机构地区：[1]湖南环境生物学院,衡阳421005 [2]中南民族大学化学与材料科学学院催化材料科学湖北省暨国家民委-教育部共建重点实验室,武汉430074

出　　处：《中南民族大学学报（自然科学版）》2008年第3期17-21,共5页Journal of South-Central University for Nationalities：Natural Science Edition

基　　金：国家自然科学基金资助项目(20702064);中南民族大学自然科学基金资助项目(YZZ07007)

摘　　要：为改善催化剂的溶解性能,以寻求更高效的光催化剂,以1,3-二亚氨基异吲哚啉和2,3-二氰基-1,4-二噻英为原料,用固相法合成了不对称型1,4-二噻英-二苯基四氮杂卟啉铁FePcPz(dtn)4及其氯代改性FePcClPz(dtn)4.对所得产物进行了UV-Vis、IR、X-射线光电子能谱(XPS)表征.考察了产物的溶解性能,利用高效液相色谱法对产物进行了分离研究.To improve the solubility properties and find highly efficient photocatalysis materials, the assymmetric iron （ Ⅱ ） 1,4-dithiin-diphenyl porphyrazine FePcPz（dtn）4 and its chloridized ,FePcC1Pz（dtn）4 were synthesized from 2,3-dithiolate-1,4-dithiin and 1,3-diiminoisoindoline by solid-state method. The products were analyzed by HPLC and their structures were characterized by UV＇-vis, FT-IR and X-ray photoemission spectroscopies and their solubility properties were investigated roughly.

关 键 词：1 3-二亚氮基异吲哚啉 2 3-二氰基-1 4-二噻英 固相法 表征 高效液相色谱 

分 类 号：TB383[一般工业技术—材料科学与工程]