二氧化碳与环氧化合物合成环状碳酸酯的研究进展  

Recent Advances in the Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides

作　　者：高志文[1] 肖林飞[1] 陈静[1] 夏春谷[1] 

机构地区：[1]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000

出　　处：《催化学报》2008年第9期831-838,共8页

基　　金：国家自然科学基金重点项目(20533080);国家杰出青年基金(20625308)

摘　　要：二氧化碳作为温室气体和储量大、无毒且可循环利用的碳资源,其化学利用受到了人们的广泛关注.二氧化碳与环氧化合物通过环加成反应制备环状碳酸酯是二氧化碳化学法利用最为有效的途径之一.本文综述了近年来该反应的研究进展,讨论了催化剂作用下的反应机理.In recent years, much attention has been paid to the chemical utilization of carbon dioxide because it is one of the green house gases and is considered a recyclable, abundant, and non-toxic C1 resource. The synthesis of cyclic carbonates from carbon dioxide and epoxides is one of the most effective routes for chemical utilization of carbon dioxide as a C1 building block. The latest progress in the synthesis of cyclic carbonates from carbon dioxide and epoxides was reviewed, and the catalytic reaction mechanism was discussed.

关 键 词：二氧化碳 环氧化合物 环状碳酸酯 离子液体 

分 类 号：TQ225.52[化学工程—有机化工]