分光光度法同时测定无机多组分体系的研究 Ⅵ 锑、锡和锗的同时测定  

STUDIES ON SIMULTANEOUS SPECTROPHOTOMETRIC DETERMINATION OF INORGANIC MULTICOMPONENT SYSTEM Ⅵ.DETERMINATION OF ANTIMONY,GERMANIUM AND TIN IN RIVER SEDIMENT

作　　者：邱孙青[1] 汪炳武[1] 王保宁[1] 

机构地区：[1]中国科学院长春应用化学研究所

出　　处：《分析化学》1989年第12期1057-1061,共5页Chinese Journal of Analytical Chemistry

基　　金：国家自然科学基金

摘　　要：本文提出一个快速同时分光光度测定锑、锡和锗的方法。锑、锡和锗经磷酸三丁酯萃取后,用苯基萤光酮显色,各配合物重叠光谱的相互干扰用CPA-矩阵法处理,方法简捷,灵敏度及准确度均较好,用于合成样品及河流沉积物中锑、锡和锗的测定,获得满意的结果。A simple method for simultaneous spectrophotometric determination of Sb, Sn and Ge has been developed. Sb, Sn and Ge were extracted by tributyl phosphate (TBP) and then reacted with phenylfluorone. The interference of overlapping spectra of complexes for spectrophotometric determination of these three elements can be overcome by using the computation of CPA (the inverse expression of Beer-lambert's law)matrix method.The method was applied to the determination of Sb,Sn and Ge in the river sediment with satisfactory results.

关 键 词：锑 多组分体系 分光光度法 锡 锗 

分 类 号：O614.43[理学—无机化学]