乙炔羰基合成的研究进展  

Research Progress on Acetylene Carbonylation

作　　者：唐聪明[1,2,3] 曹平[1,2,3] 曾毅[1,2] 杨先贵[1,2] 王公应[1,2] 

机构地区：[1]中国科学院成都有机化学研究所,四川成都610041 [2]常州化学研究所,江苏常州213164 [3]中国科学院研究生院,北京100049

出　　处：《石油化工》2008年第10期1089-1094,共6页Petrochemical Technology

基　　金：国家科技支撑计划资助项目(2006BAE02B01)

摘　　要：对乙炔碳基合成丙烯酸(酯)、丁二酸酸酐、丁烯二酸二丁酯和丙烯醛等系列有机产品进行了综述。重点探讨了乙炔碳基合成丙烯酸(酯)的催化剂和反应工艺条件。镍基和钯基催化剂是催化乙炔羰基合成丙烯酸(酯)的良好催化剂,同时钯基催化剂也是催化乙炔羰基合成丁二酸酸酐和丁烯酸二酯的良好催化剂。镍聚和钯基催化剂的复合及负载化是今后乙炔羰基合成研究的主要发展方向。Research of acetylene carbonylation to acrylic acid, acrylate, succinic anhydride, dibutyl ester of butene diacid, acrolein, etc. was reviewed. Catalysts and reaction conditions used in acetylene carbonylation to acrylic acid or ester were mainly introduced. Both nickel catalyst and palladium catalyst were excellent in the carbonylation of acetylene to acrylic acid or ester. Palladium catalyst was also excellent in carbonylation of acetylene to succinic anhydride and dibutyl ester of butene diacid. Developments of composite catalysts and supported catalysts would be the major trend of the research for acetylene carbonylation.

关 键 词：乙炔 羰基合成 丙烯酸 丙烯酸酯 丁二酸酸酐 丙烯醛 

分 类 号：TQ032.4[化学工程]