The differential interference angle of ~2Π [Case(a)] diatom on rotational energy transfer in NO (X^2Π ) collision with He,Ne and Ar system  被引量:1

The differential interference angle of ~2Π [Case(a)] diatom on rotational energy transfer in NO (X^2Π ) collision with He,Ne and Ar system

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作  者:李永庆 李健 赵丽娜 倪艳清 马凤才 

机构地区:[1]Department of Physics, Liaoning University [2]Departamento de Qu?mica, Universidade de Coimbra [3]Department of Science, Shenyang Institute of Aeronautical Engineering [4]Center for Science and Technology Experiment, Bohai University

出  处:《Chinese Physics B》2008年第10期3649-3654,共6页中国物理B(英文版)

基  金:Project supported by the National Natural Science Foundation of China (Grant No 10374040);the Fund of the Educational Department of Liaoning Province, China (Grant No 20060347)

摘  要:To study theoretically the relationship between the differential interference angle and the scattering angle in collisional quantum interference (CQI), we have investigated the differential interference angle of the atom-diatomic [case(a)] molecule system in detail. For the 2∏ electronic state in Hund's case (a), the degree of the differential interference is also discussed. The differential interference angles of NO(X^2∏) are calculated quantitatively for the rotational energy transfer in Hund's case (a) induced by collision with He, Ne and Ar atoms. The method to calculate the differential interference angle is presented. Several factors that affect the differential interference angle are investigated. Finally the variation of the differential interference angle with the impact parameter and relative velocity is discussed.To study theoretically the relationship between the differential interference angle and the scattering angle in collisional quantum interference (CQI), we have investigated the differential interference angle of the atom-diatomic [case(a)] molecule system in detail. For the 2∏ electronic state in Hund's case (a), the degree of the differential interference is also discussed. The differential interference angles of NO(X^2∏) are calculated quantitatively for the rotational energy transfer in Hund's case (a) induced by collision with He, Ne and Ar atoms. The method to calculate the differential interference angle is presented. Several factors that affect the differential interference angle are investigated. Finally the variation of the differential interference angle with the impact parameter and relative velocity is discussed.

关 键 词:collisional quantum interference rotational energy transfer interference angle longrange interaction potential 

分 类 号:O56[理学—原子与分子物理] O413.1[理学—物理]

 

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