水泥石脱水相结构特征及其再水化能力(英文)  

STRUCTURAL CHARACTERISTICS OF DEHYDRATED PHASE OF HARDENED CEMENT PASTE AND ITS REHYDRATING ABILITY

作　　者：吕林女[1] 何永佳[2] 胡曙光[2] 

机构地区：[1]武汉理工大学理学院 [2]硅酸盐材料工程教育部重点实验室,武汉430070

出　　处：《硅酸盐学报》2008年第10期1343-1347,共5页Journal of The Chinese Ceramic Society

基　　金：硅酸盐材料工程教育部重点实验室开放基金(SYSJJ2007–03);国家自然科学基金(50508034)资助项目

摘　　要：将水泥石在不同温度进行低温煅烧,得到不同的脱水相物质,通过热重–差示扫描热分析、X射线衍射、红外光谱及29Si核磁共振等对水泥石在400,650℃及900℃的脱水相结构特征及其再水化性能、再水化产物的结构特征进行研究。结果表明:在400℃,由水化硅酸钙(C–S–H)凝胶脱水生成了无定形相,在650℃生成了不完全结晶的β-硅酸二钙(C2S),而900℃脱水相中存在结晶程度高的β-C2S。在再水化过程中,400℃和650℃脱水相水化生成了C–S–H凝胶,并且650℃脱水相的水化活性和水化产物聚合程度更高;900℃脱水相的水化活性极低,水化前后矿物结构特征几乎没有发生变化。Hardened cement paste was calcined at different low temperatures, and various dehydrated phases were acquired. Thermogravimetric-differential scanning calorimeter （TG-DSC）, X-ray diffraction, infrared and 29Si nuclear magnetic resonance were used to investigate the structural characteristics, rehydration ability and rehydrating products structure of dehydrated phases prepared at 400, 650 ℃and 900℃. The results show that, at 400 ℃, amorphous phase was generated_in the dehydrating process of calcium silicate hydrate （C-S-H） gel. At 650 ℃, incompletely crystallized β-dicalcium silicate （C2S） was produced, and at 900℃, well-crystallized β-C2S was acquired. In the rehydration process, the dehydrated phases prepared at 400 ℃ and 650 ℃ reacted with water and produced C-S-H gel; the hydration activity of the latter, and the polymerization level of its hydration product were higher. However, the dehydrated phase prepared at 900 ℃ showes little rehydration ability; there is almost no change in the structural characteristic before and after the hydration process.

关 键 词：水泥石 脱水相 结构特征:再水化 水化活性 

分 类 号：TQ172[化学工程—水泥工业]