7-氯-[1,2,3,4]-四氢吩嗪-[2,3]-并富勒烯[60]的合成  

The synthesis of 7-chloro-[1,2,3,4]-tetrahydrophenazine-[2,3]-fullerene C_(60)

作　　者：文丽君[1] 曾和平[2] 杨定乔[2] 

机构地区：[1]海南医学院药学系,海南海口571101 [2]华南师范大学化学与环境学院,广东广州510631

出　　处：《化学研究与应用》2008年第10期1377-1380,共4页Chemical Research and Application

基　　金：国家自然科学基金资助项目(20071012)

摘　　要：7-chloro-[1,2,3,4]-tetrahydrophenazine-[2,3]-fullerene C60 has been firstly prepared by the Diels-Alder reaction of C60 with 6-chloro-2,3-bis(bromomethyl)-quinoxaline,which is obtained by the condensation reaction of 1,4-dibromo-2,3-butanedione with 4-chloro-1,2-phenylene-diamine.The structure of the compound is identified by UV,IR,MS,1H NMR and 13C NMR.7-chloro-[ 1,2,3,4]-tetrahydrophenazine-[ 2,3 ]- fullerene C60 has been firstly prepared by the Diels-Alder reaction of C60 with 6-ehloro-2, 3-bis （ bromomethyl ） -quinoxaline, which is obtained by the condensation reaction of 1,4-dibromo-2, 3- butanedione with 4-ehloro-1,2-phenylene-diamine. The structure of the eompotmd is identified by UV, IR, MS,^1H NMR and ^13C NMR.

关 键 词：7-氯一[1 2 3 4]-四氢吩嗪-[2 3]-并富勒烯[60] 富勒烯衍生物 Diels—Alder环加成反应 合成 

分 类 号：O621.3[理学—有机化学]