八联(硫丁基)四氮杂卟啉及其镁(Ⅱ)、铜(Ⅱ)配合物的合成与表征  

Synethesis and Characterization of Octakis (Butylthio)-Tetraazaporphyrin and Its Mg(Ⅱ),Cu(Ⅱ) Coordination Compound

作　　者：黎凌云[1,2] 汤跃群[1,2] 黄道昌 

机构地区：[1]湖南农业大学 [2]长沙电力学院

出　　处：《长沙水电师院学报（自然科学版）》1997年第3期266-269,共4页

摘　　要：以自制的１，２—二氰基—１′，２′—二硫丁基乙烯为单体，用板模法合成了八联（硫丁基）四氮杂卟啉Ｈ２Ｃ１６Ｎ８（ＳＣＨ２ＣＨ２ＣＨ２ＣＨ３）８及其镁（Ⅱ）、铜（Ⅱ）配合物ＭｇＣ１６Ｎ８（ＳＣＨ２ＣＨ２ＣＨ２ＣＨ３）８、ＣｕＣ１６Ｎ８（ＳＣＨ２ＣＨ２ＣＨ２ＣＨ３）８．三种新化合物由元素分析、红外光谱和紫外—可见光谱表征，并对这三种化合物的溶解性进行了研究．The Octakis(butylthio)-tetraazaporphyrin H 2C 16 N 8(SCH 2CH 2CH 2CH 3) 8 and its Mg(Ⅱ),Cu(Ⅱ) metal coordination compound MgC 16 N 8(SCH 2CH 2CH 2CH 3) 8,CuC 16 N 8(SCH 2CH 2CH 2CH 3) 8 have been synthesized according to the template reaction methed from 1,2-dicyano-1′,2′-bis(butylthio)ehylene. The three new compounds were characterized by elemental analysis, IR,UV-Vis Spectra .The dissolubility of the three compounds have been studied.

关 键 词：含硫四氮杂卟啉 配合物 镁 铜 

分 类 号：O641.4[理学—物理化学]