C60Pt(BINAP)金属配合物的合成表征与光电性能研究  

Synthesis and Characterization and Photoelectric Property of Fullerene Complex C_(60)Pt(BINAP)

作　　者：覃世辉[1,2] 吴振奕[1] 杨绳岩[1] 詹梦熊[1] 

机构地区：[1]厦门大学化学化工学院,厦门361005 [2]广西河池学院化学与生命科学系,宜州546300

出　　处：《无机化学学报》2008年第10期1626-1630,共5页Chinese Journal of Inorganic Chemistry

基　　金：福建省自然科学基金资助项目(No.E04100001,E0110002)。

摘　　要：本文利用配体取代法合成了C60Pt(BINAP)新型富勒烯膦金属配合物,采用质谱、元素分析、紫外-可见吸收光谱、红外吸收光谱、光电子能谱等对该产物进行了表征,并测定了其在光化学电池中的光伏效应。光伏效应测试结果表明:在BQ/H2Q与I2/I3-介质溶液中镀层厚度为1～2μm时,具有较好的光电转换性能,光生电压值最高达358mV。A fullerene-phosphine metal complex, C60Pt（BINAP）, product was characterized by MS, elemental analysis, UV-Vis, was synthesized by ligand substitution method. The IR and XPS. The photovohaic performances of the complex was determined in the photochemistry cell. The results showed that the fullerene-phosphine metal complex exhibited high photoelectric conversion property, especially under the conditions of BQ/H2Q and I3-/Iredox couples, and 1～2μm of thickness of the film, the maximum value of photovohage was 358 mV.

关 键 词：富勒烯 联萘二苯膦 金属配合物 光伏效应 

分 类 号：O614.826[理学—无机化学] O613.71[理学—化学]