增效试剂对过氧化物模拟酶催化显色体系的增效作用——Fe-TPPS_4-4-AAP-苯酚衍生物-H_2O_2体系  

Enhanced Effect of Enhancing Agents on the Oxidation Reaction Catalyzed by Mimetic Horseradish Peroxidase ——Fe TPPS 4 4 AAP Phenol H 2O 2 System

作　　者：苏小笛[1,2] 刘昭林[1,2] 朱敏[1,2] 沈含熙 

机构地区：[1]天津大学应用化学系 [2]南开大学化学系

出　　处：《应用化学》1997年第3期33-36,共4页Chinese Journal of Applied Chemistry

摘　　要：本文以β－环糊精（β－ＣＤ）和表面活性剂为增效试剂，分别研究了它们对以Ｆｅ－ｍｅｓｏ－（四（４－磺基苯）卟啉）（Ｆｅ－ＴＰＰＳ４）为催化剂，催化过氧化氢氧化４－氨基安替比林（４－ＡＡＰ）与苯酚衍生物显色反应的速度和灵敏度的影响，发现β－ＣＤ和十二烷基苯磺酸钠（ＳＤＢＳ）对该体系具有明显的增效作用．在３×１０－３ｍｏｌ／Ｌβ－ＣＤ存在下，测定Ｈ２Ｏ２的灵敏度比文献报道的提高了１．５６倍．利用ＳＤＢＳ浓度与催化显色反应初速度的增加值之间的线性关系。The enhanced effect of β cyclodextrin( β CD) or surfactants on the oxidation reaction of H 2O 2 with 4 aminoantipyrine and phenol, using iron (4 sulphophenyl) porphine (Fe TPPS 4) as catalyst has been studied. It is indicated that the initial rate and sensitivity of this color reaction are increased with the added amount of β CD or sodium dodecylbenzene sulfate(SDBS). A sensitive method for the determination of H 2O 2 in the presence of β CD has been developed. Trace amount of SDBS can be determined based on the linear relationship between the increment of the reaction rate and the concentration of the surfactant.

关 键 词：β-环糊精 SDBS 双氧水 增效 铁卟啉 显色反应 

分 类 号：O613.3[理学—无机化学] O647.2[理学—化学]