活性聚甲基丙烯酸甲酯活性链和溴甲基化聚苯乙烯偶合反应制备接枝共聚物  

Synthesis of Graft Copolymer by Coupling Reaction of Living Polymethyl Methacrylate with Bromomethylated Polystyrene

作　　者：邹友思[1] 邱志平[1] 张景辉 潘容华[1] 

机构地区：[1]厦门大学化工系

出　　处：《合成化学》1997年第2期123-126,共4页Chinese Journal of Synthetic Chemistry

摘　　要：采用基团转移聚合、阴离子聚合以及高分子偶合反应的方法，合成了一种结构明确、链长均匀、分子量可控的聚苯乙烯接枝聚甲基丙烯酸甲酯。主链聚苯乙烯由阴离子聚合得到，并进行溴甲基化。支链活性聚甲基丙烯酸甲酯由基团转移聚合制备。经偶合反应后得到分子量为３×１０４～７×１０４、多分散性指数Ｄ为１．２～１．４的接枝共聚物。用１ＨＮＭＲ，ＧＰＣ和ＤＳＣ表征接枝产物。和均聚物相比，共聚物的玻璃化温度较低。A novel well defined graft copolymer(PS g PMMA) with control over the length of both backbone and side chain was synthesized by coupling reaction of living polymethyl methacrylate with bromomethylated polystyrene. The backbone polymer was prepared by anionic polymerization of styrene with n butyllithium followed by bromomethylation using C 8H 17 OCH 2Br/SnCl 4. The living PMMA was prepared by group transfer polymerization of MMA. The graft copolymers with narrow molecular weight distribution, D=1.2￣1.4, at the Mn of around 3×10 4￣7×10 4 were obtained. Structure of the product was characterized by 1H NMR, 13 C NMR, GPC and DSC. Comparing with the homopolymer PS and PMMA, the copolymer has lower glass temperature.

关 键 词：聚甲基丙烯酸 甲酯 溴甲基化 聚苯乙烯 接枝共聚 

分 类 号：TQ325.2[化学工程—合成树脂塑料工业] TQ325.7