1-酰基-4-氯环己烷与取代芳烃的区域与立体选择性反应(英文)  

Regio and Stereoselective Reactin of 1 Acyl 4 chlorocyclohexane with Substituted Aromatics

作　　者：杜卫红[1] 安忠维[1] 徐茂梁[1] 李志斌[1] 马冬华 王凤山[1] 孔繁玲[1] 

机构地区：[1]西安近代化学研究所

出　　处：《合成化学》1997年第2期205-208,共4页Chinese Journal of Synthetic Chemistry

摘　　要：从环己烯合成了１－酰基－４－氯环己烷，发现其在ＡｌＣｌ３催化下与苯、氯苯、溴苯等优先生成反式－１－芳基－４－酰基环己烷，与联苯反应时选择性较差。Acyl 4 chlorocyclohexane was synthesized by acylation of cyclohexene. GC, GC MS and 1H NMR analyses showed that this compound reacts high regio and stereoselectively with benzene, chlorobenzene and bromobenzene to give trans 1 acyl 4 arylcyclohexanes under the catalysis of AlCl 3. Poor selectivity was observed when it reacts with biphenyl.

关 键 词：环己烯 酰基 氯环己烷 液晶 环己烷衍生物 

分 类 号：O753.2[理学—晶体学] O624.11