新型手性Schiff碱配体及其铜(Ⅱ)配合物的设计、合成与表征  

Design,Synthesis and Characterization of a New Chiral Schiff Base Ligand and Its Cu(Ⅱ) Complexes

作　　者：管月清[1] 刘晓明[1] 王倩[1] 陈丽慧[1] 周国斌[1] 

机构地区：[1]山东科技大学化学与环境工程学院,山东青岛266510

出　　处：《山东科技大学学报（自然科学版）》2008年第5期81-84,共4页Journal of Shandong University of Science and Technology(Natural Science)

基　　金：国家自然科学基金项目(20662005);山东省教育厅科技计划项目(J07WC06)

摘　　要：Schiff碱金属配合物不仅具有抑菌、杀菌、抗肿瘤、抗病毒等方面的重要应用,而且在催化领域具有广泛的应用前景。本文以价廉、易得的葡萄糖为起始原料,经多步反应高产率地合成出了一类新型手性Schiff碱及其铜(Ⅱ)配合物,用IR,1H NMR对手性Schiff碱及其铜(Ⅱ)配合物进行了结构表征。到目前为止,该类手性Schiff碱铜(Ⅱ)配合物合成研究尚未见文献报道。The Schiff base metal complexes have been of interest in coordination for many years due to their biological activities including antibacterial, antifungal, anticancer and herbicidal activities. On the other hand, they are a class of important compounds in catalysis field. One type of new chiral Schiff base and it＇s coordination compounds of copper （Ⅱ） have been synthesized by using D-glucose as the starting material through multi-step reaction and the products are characterized by IR spectroscopy and ^1H NMR. To the best of our knowledge, such synthesis of chiral Schiff base copper （Ⅱ） complex has not been reported previously.

关 键 词：葡萄糖 手性SCHIFF碱 铜(Ⅱ)配合物 合成 表征 

分 类 号：O621[理学—有机化学]