纳米Fe粒子包覆微米Al复合材料的制备与表征  

Preparation & characterization of composite with micron Al coating in nanometer Fe particles

作　　者：王毅[1] 姜炜[1] 张先锋[2] 程志鹏[1] 安崇伟[1] 郭效德[1] 李凤生[1] 

机构地区：[1]南京理工大学国家特种超细粉体工程技术研究中心,江苏南京210094 [2]南京理工大学机械工程学院,江苏南京210094

出　　处：《功能材料》2008年第11期1900-1902,共3页Journal of Functional Materials

基　　金：国家自然科学基金资助项目(50602024)

摘　　要：采用置换法，通过在溶液中引入F^-离子，实现了弱酸性条件下Fe纳米粒子在微米Al粉表面定量、快速地化学沉积，制备出具有核壳结构的Fe／Al微纳米复合粒子。将该复合粒子中的Al核用盐酸溶蚀后得到由纳米Fe粒子组成的空心球壳。利用SEM、EDS、XRD、BET和TG／DSC对产物进行了相应地表征，结果表明，微米Al核表面被一层粒径约为30～60nm的Fe纳米粒子致密包覆，Fe／Al复合粉体的比表面积达到11．993m^2／g较包覆前的1．082m^2／g增加了11倍，且Fe／Al微纳米复合粉体与O2反应的活性明显高于原料Al粉。Via introducing of F- ions, a kind of core-shell Fe/Al nanocomposite had been prepared by displacement method, in which the micron Al grain were coated in a lay of nanometer Fe particles. When as-prepared Fe/Al nanocomposites were immersed into hydrochloric acid until there was no effervescence, the porous shellshaped products composing of nanometer Fe particles can be obtained. SEM, EDS, XRD, BET and TG/DSC analysis were employed to characterize the samples. Results indicated that Al core were covered by the tightly agglomerated Fe nanoparticles of 30-60nm in size, showing honeycomb-like coarse surface. After coating, the specific surface area has an 11-fold increase from 1. 082 to 11. 993m^2/g. Moreover, the thermal reactivity of Fe/ Al nanocomposites with O2 is obviously higher than that of raw Al powders.

关 键 词：复合材料 表面包覆 置换法 Al粉 纳米Fe粒子 

分 类 号：TB331[一般工业技术—材料科学与工程]