烯丙基卤和锡与醛、酮反应合成高烯丙基醇  

Synthesis of Homoallyl Alcohol from Carbonyl Compounds by Allyl Halide and Tin

作　　者：吴世晖[1] 黄邦洲[1] 朱天民[1] 姚丹姝[1] 初永亮 

机构地区：[1]复旦大学化学系

出　　处：《化学学报》1990年第4期372-376,共5页Acta Chimica Sinica

摘　　要：烯丙基溴或烯丙基碘和锡能以较高的产率与含有羟基、酚羟基、硝基、溴等活性基团的羰基化合物作用合成相应的高烯丙基醇.文中讨论了不同卤素以及溶剂性质、水的含量对反应的影响.Homoallyl alcohol containing hydroxy,phonolic hydroxyl,aromatic nitro and,bromo groups can be obtained directly from the reaction of corresponding carbonyl compounds with allyl halide and tin powder in good yields.The effect of solvents and the amount of water present on product yields were discussed.

关 键 词：烯丙基卤 锡 醛 酮 高烯丙基醇 

分 类 号：O623.412.1[理学—有机化学]