漆姑草中酚性成分研究  

Phenolic compounds from Sagina japonica

作　　者：贾爱群[1,2] 谭宁华[1] 周俊[1] 

机构地区：[1]中国科学院昆明植物研究所,云南昆明650204 [2]南京理工大学化工学院,江苏南京210014

出　　处：《中草药》2008年第11期1609-1612,共4页Chinese Traditional and Herbal Drugs

摘　　要：目的研究漆姑草中的酚性化学成分。方法采用硅胶柱色谱、Sephadex LH-20凝胶色谱及RPC-18柱色谱进行分离纯化,并运用波谱方法对所分得化合物进行结构鉴定。结果从漆姑草中分得9个酚性化合物,经波谱解析分别确定为:E-对甲氧基肉桂酸甲酯(Ⅰ)、伞形花内酯(Ⅱ)、7-甲氧基香豆素(Ⅲ)、5,7-二羟基香豆素(Ⅳ)、5,7-二甲氧基香豆素(Ⅴ)、7-O-β-D-葡萄吡喃糖-6-C-β-D-木糖吡喃糖-5,4′-二羟基黄酮(Ⅵ)、5,7,2′-三羟基-8-甲氧基黄酮(Ⅶ)、5,7-二羟基-8,2′-二甲氧基黄酮(Ⅷ)、5,7,3′,4′-四羟基-6-甲氧基黄酮(Ⅸ)。结论所有化合物均为首次从该植物中分得。Objective To study the phenolic compounds from Sagina japonica. Methods The separation and purification were carried out by silica gel Sephadex LH-20 gel and RP C-18 colomn chromatography. The structures were identified by spectra. Results Nine phenolic compounds were isolated from S. japonica. They were identified as： p-E-methoxy cinnamic acid methyl ester （Ⅰ ）, umbelliferone （Ⅱ）, 7-methoxy coumarin （Ⅲ）, 5, 7-di-hydroxy coumarin （Ⅳ）, 5, 7-di-methoxy coumarin （Ⅴ）, cerarvensim7-O-glucoside （Ⅵ）, 5, 7, 2′-trihydroxy-8-methoxy flavone （Ⅶ）, 5, 7-di- hydroxy-8, 2＇-di-methoxy flavone （Ⅷ）, 5, 7, 3＇, 4＇-tetrahydroxy-6-methoxy flavone （Ⅸ）. Conclusion All of these compounds are first isolated from S. japonica.

关 键 词：漆姑草 石竹科 酚性成分 

分 类 号：R284.1[医药卫生—中药学]