一维链状叠氮桥联的铜配位聚合物[Cu(N_3)_2(C_6H_8N_2)]_n的合成、晶体结构和磁性  

Synthesis, Structure and Magnetic Property of Coordination Polymer [Cu(N_3)_2(C_6H_8N_2)]_n with 1D Chain

作　　者：沈康[1] 朱敦如[1] 吴艳飞[1] 沈旋[1] 

机构地区：[1]南京工业大学化学化工学院材料化学工程国家重点实验室,南京210009

出　　处：《无机化学学报》2008年第11期1912-1915,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金项目(No.20771059);教育部留学回国人员科研启动基金;江苏省自然科学基金项目(No.BK2008371)资助

摘　　要：A new one-dimensional chain complex [Cu(N3)2(C6H8N2)]n (C6H8N2=(2-aminomethyl)pyridine) has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in triclinic space group P1, with a=0.690 1(2) nm, b=0.825 1(3) nm, c=0.995 3(3) nm, α=67.154(5)°, β=72.898 (5)°, γ=65.462 (5)°, V=0.469 1 (3) nm3, Z=2. Magnetic susceptibility measurement indicates that there is a weak ferro-magnetic exchange coupling between Cu(Ⅱ) ions. CCDC: 686151.A new one-dimensional chain complex [Cu（N3）2（C6H8N2）]n （C6H8N2=（2-aminomethyl）pyridine） has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in triclinic space group P1, with a=0.690 1（2） nm, b=0.825 1（3） nm, c=0.995 3（3） nm, α=67.154（5）°, β=72.898 （5）°, γ=65.462 （5）°, V=0.469 1 （3） nm^3, Z=2. Magnetic susceptibility measurement indicates that there is a weak ferro-magnetic exchange coupling between Cu（Ⅱ） ions. CCDC： 686151.

关 键 词：铜配合物 晶体结构 叠氮桥联 磁性 

分 类 号：O614.121[理学—无机化学]