烯丙基COPNA树脂的合成与性能  

Synthesis and Properties of Allyl-COPNA Resin

作　　者：赵俭波[1] 林起浪[1] 陈勇[1] 柯余良[1] 

机构地区：[1]福州大学材料科学与工程学院,福建福州350108

出　　处：《高分子材料科学与工程》2008年第11期51-53,57,共4页Polymer Materials Science & Engineering

基　　金：福建省青年创新基金(2006F3067);福州大学人才基金(XRC-0513);福州大学科技发展基金(2006-XY-1)

摘　　要：以1-萘酚、对苯二甲醇、烯丙基氯等合成出新型缩合多核芳烃(COPNA)树脂。采用FT-IR和1H-NMR研究了COPNA树脂的化学结构;通过凝胶分析研究了COPNA与双马来亚酰胺的共聚反应性;采用TG-DTG研究了这种共聚树脂的热稳定性。研究表明,COPNA树脂结构中含有烯丙基活性基团,可与BMI发生共聚反应制备耐热性优良的树脂体系。In order to obtain a high-performance resin matrix for advanced polymeric composites （APC）, a new condensed polynuclear aromatic （COPNA） resin containing allyl was synthesized using 1-hydroxy naphthalene, 1, 4-benzenedimethanol, allyl-chlorine, and so on. The chemical structures of the COPNA resin were characterized by FT-IR and ^1H-NMR, and the copolymerization reactivity of the COPNA resin and bismaleimide （BMI） was studied through gel analysis. Moreover, TG-DTG was employed to study the thermal behavior of the copolymer of the COPNA resin and BMI. The results show that the COPNA resin has high reactivity with BMI due to the active group of allyl, and the resulting copolymer possesses excellent thermo-stability and high coke value.

关 键 词：烯丙基 缩合多核芳烃(OOPNA树脂) 合成 性能 

分 类 号：TQ324.9[化学工程—合成树脂塑料工业]