锰八面体分子筛的合成、表征及其对二甲醚燃烧的催化性能(英文)  

Synthesis and Characterization of Manganese Oxide Octahedral Molecular Sieve and Its Catalytic Performance for DME Combustion

作　　者：余林[1] 孙明[1] 余坚[1] 余倩[1] 郝志峰[1] 李朝圣[1] 

机构地区：[1]广东工业大学轻工化工学院,广东广州510006

出　　处：《催化学报》2008年第11期1127-1132,共6页

基　　金：Supported by Guangdong Natural Science Foundation (04205301);Project of Science and Technology of Guangdong(2005B10201053);Project of Science and Technology of Guangzhou (2006 J1-C0501);Key Programin Natural Science of Higher Edu-cation of Guangdong (06Z011)

摘　　要：以高锰酸钾和马来酸为原料,以聚乙二醇单甲醚(MPEG)为模板剂,采用溶胶凝胶法合成了锰八面体分子筛(OMS-2),并将其用于二甲醚的催化燃烧反应.XRD,FT-IR和UV-Vis结果表明,合成的材料为隐钾锰矿型的锰氧化物.TEM结果表明合成的材料具有棒状的外形结构,其中MPEG起模板导向剂的作用.O2-TPD和H2-TPR结果表明合成的OMS-2材料容易还原,富有晶格氧.OMS-2材料在二甲醚催化燃烧中表现出优异的催化性能,能够在较低的温度下将二甲醚完全转化为CO2和H2O,晶格氧在该反应中起非常重要的作用.Manganese oxide octahedral molecular sieve （OMS-2） was prepared by the sol-gel method using KMnO4 and maleic acid in the presence of methoxypolyethylene glycols （MPEG） and used for the catalytic combustion of dimethyl ether （DME）. XRD, FT-IR and UV-Vis data confirmed that the formation of cryptomelane-type manganese oxide. TEM results showed that the OMS-2 had rodlike shape and the MPEG played a role as a structure-directing agent in the OMS-2 formation. O2-TPD and H2-TPR results indicated that the OMS-2 was rich in facile lattice oxygen, can activate oxygen and be easily reduced by He. The OMS-2 possessed excellent catalytic performance for DME combustion, and could convert DME to CO2 and H2O at a relatively low temperature. The lattice oxygen played a key role in the DME combustion.

关 键 词：氧化锰 八面体分子筛 二甲醚 燃烧 二氧化碳 水 

分 类 号：O643.32[理学—物理化学]