纳米碳纤维负载钯催化剂在Heck反应中的应用——载体相互作用的影响(英文)  

Carbon Nanofiber-Supported Pd Catalysts for Heck Reaction:Effects of Support Interaction

作　　者：朱俊[1] 赵铁均[1,2] Ingvar KVANDE 陈德[2] 周兴贵[1] 袁渭康[1] 

机构地区：[1]华东理工大学化学工程联合国家重点实验室,上海200237 [2]挪威科技大学化学工程系,挪威特隆赫姆7491

出　　处：《催化学报》2008年第11期1145-1151,共7页

基　　金：Supported by the National Natural Science Foundation of China (20776041,20490200,20476026);the Creative Team Development Project of Ministry of Education of China,the 111 Project of China (IRT0721);Strategy Materials, Norwegian Universityof Science and Technology, Norway

摘　　要：使用多元醇还原法制备了均匀分散的钯纳米颗粒.将钯纳米颗粒负载于板式、鱼骨式和管式纳米碳纤维,得到稳定、可重复使用的非均相催化剂.实验结果表明,钯纳米胶粒同载体之间的电位差对钯在载体上的负载量、粒子大小以及Heck反应中钯的溶失量有很大的影响.在制备过程中,增加钯纳米胶粒同纳米碳纤维表面的电位差能够大大降低钯在Heck反应中的流失.催化剂的反应活性随钯粒子的增大而降低.Well-dispersed palladium nanoparticles were synthesized by means of polyol reduction method. In order to prepare stable and reusable heterogeneous catalysts, palladium nanoparticles were supported on platlet carbon nanofiber （pCNF）, fishbone carbon nanofibers （fCNF）, and tubular carbon nanofibers （tCNF）. It was found that the Pd loading and the particles size as well as the amount of Pd leaching during the Heck reaction were strongly related to the potential difference between the CNF surfaces and the palladium colloids. Pd leaching in the Heck reaction can be significantly suppressed by increasing potential difference between the CNF surfaces and the palladium colloids during catalyst preparation. The Pd activity decreased exponentially with the Pd particle size.

关 键 词：纳米碳纤维 钯 等电点 HECK反应 非均相催化剂 

分 类 号：O643.36[理学—物理化学]