Effects of temperature and initial molar ratio of Na_2O to Al_2O_3 on agglomeration of fine Al(OH)_3 seed in synthetic Bayer solution  

作　　者：张斌 陈启元 李洁 尹周澜 

机构地区：[1]College of Materials Science and Engineering,Hunan University [2]School of Chemistry and Chemical Engineering,Central South University

出　　处：《Journal of Central South University of Technology》2008年第6期786-790,共5页中南工业大学学报（英文版）

基　　金：Project(2005CB623702)supported by the Major State Basic Research and Development Program of China;Project(20476107) supported by the National Natural Science Foundation of China

摘　　要：Fine Al（OH）3 crystals were aggregated from supersaturated aluminate solution in the batch reaction tanks. By means of laser particle size analyzer and scanning electron microscopy, the influences of temperature and initial molar ratio of Na2O to Al2O3 （aK） on agglomeration of fine seed in Bayer process were investigated. The results show that agglomeration is almost finished in 8 h, and seeds with size less than 2 μm are easily aggregated together, and almost disappear in 8 h under the optimal process conditions. In the aluminate solution with the same moderate initial aK, when the reaction temperature reaches 75 ℃, the secondary nucleation does not occur, and the effect of agglomeration is better. And at the same reaction temperature, when the initial aK is 1.62, the initial supersaturation of aluminate solution is moderate, the binders on the surfaces of the seed are enough to maintain the agglomeration process, and the agglomeration degree is better. From SEM images, agglomeration mainly occurs in the fine particles, the combinations among the fine particles are loose and the new formed coarse crystal shapes are irregular.Fine Al(OH)3 crystals were aggregated from supersaturated aluminate solution in the batch reaction tanks. By means of laser particle size analyzer and scanning electron microscopy, the influences of temperature and initial molar ratio of Na2O to Al2O3 (αK) on agglomeration of fine seed in Bayer process were investigated. The results show that agglomeration is almost finished in 8 h, and seeds with size less than 2 μm are easily aggregated together, and almost disappear in 8 h under the optimal process conditions. In the aluminate solution with the same moderate initial αK, when the reaction temperature reaches 75 ℃, the secondary nucleation does not occur, and the effect of agglomeration is better. And at the same reaction temperature, when the initial αK is 1.62, the initial supersaturation of aluminate solution is moderate, the binders on the surfaces of the seed are enough to maintain the agglomeration process, and the agglomeration degree is better. From SEM images, agglomeration mainly occurs in the fine particles, the combinations among the fine particles are loose and the new formed coarse crystal shapes are irregular.

关 键 词：sodium aluminate Bayer process screen separation AGGLOMERATION initial molar ratio of Na2O to Al2O3 

分 类 号：O614.31[理学—无机化学]