超级双相不锈钢00Cr25Ni7Mo3.5N表面原位氧化研究  

In-situ Surface Oxidation of 00Cr25Ni7Mo3.5N Supper Duplex Stainless Steel

作　　者：臧华勋[1] 李钧[1] 肖学山[1] 赵钧良[2] 江来珠[2] 

机构地区：[1]上海大学材料研究所,上海200072 [2]宝山钢铁股份有限公司,上海201900

出　　处：《钢铁》2008年第8期69-72,共4页Iron and Steel

基　　金：上海市科委重点攻关项目(065211026)

摘　　要：采用高温XRD技术研究了超级双相不锈钢00Cr25Ni7Mo3.5N表面原位氧化行为。对该钢种在空气条件下进行连续加热,选取一些温度点进行测试,研究了其表面氧化物的生长规律,并分析了第二相的析出行为。结果表明,600℃以下表面组织均为α、γ两相结构。800℃时α相开始被氧化成-αFe2O3,900℃时α相被氧化成-αFe2O3和Fe3O4,继续加热至1 000℃时α相全部氧化消失。即使温度升高到1 100℃,γ相也没有被氧化。而在空气条件下,不同温度水淬样品内部的室温组织始终保持α、γ两相结构,并且随温度增加,α相比例逐渐增加。此外,加热过程中还发现表面与内部的σ相几乎同步产生和消失。In-situ surface oxidation of 00Cr25Ni7Mo3.5N supper duplex stainless steel was studied by high temperature XRD. The samples were continually heated in the air and tested at several temperature. The growth of surface oxide was investigated and precipitation of second-phase was investigated. The results showed that the surface layer was only composed of α phase and γ phases below 600 ℃, a was oxidized to α-Fe2O3 at about 800 ℃, then to α- Fe2 O3 ＋Fe3O4 at about 900 ℃,and disappeared completely up to 1000 ℃. However, 7 was not oxidized even at up to 1100℃. The microstructure of the samples quenched from various temperatures were of α and γ, and the fraction of α phase was gradually increased with the temperature. In addition, σ phase in surface layer and interior of quenched samples was almost precipitated and dissolved simultaneously during heating.

关 键 词：双相不锈钢 原位氧化 Α-FE2O3 Σ相 

分 类 号：TG142.71[一般工业技术—材料科学与工程]