离子自组装超分子液晶的研究进展  

Recent Progress of Supramolecular Liquid Crystalline by Self-assembly via Ionicinteraction

作　　者：李凤红[1] 张宝砚[1] 梁光旭[1] 顾卫敏[1] 

机构地区：[1]东北大学分子科学与工程中心,沈阳110004

出　　处：《高分子通报》2008年第12期30-37,共8页Polymer Bulletin

基　　金：国家自然科学基金资助项目(50673105);国家863项目(2006AA02Z291)

摘　　要：离子自组装超分子液晶是超分子体系中相对较新颖和引入注意的领域,它在新型功能材料的设计中占据非常重要的位置。本文主要介绍目前文献报道的由含铵离子的液晶分子或非液晶分子与含羧基的聚合物和含磺酸离子的聚合物自组装成超分子液晶及含金属离子(锌、铜、锂、氧钒基)的金属离子配位自组装超分子液晶两大类。Supramolecules by self-assembly via ionicinteraction are a relatively new and fascinating area in supramolecular science. It will play an important role in designing new types of functional materials. This review describes two kinds of supramolecular liquid crystalline reported from the recent literatures. One is made of ammonium ion -based liquid crystalline polymer or ammonium-based non liquid crystalline polymer with polymer containing SO3 - groups and COO- groups, the other is made of metalline coordination liquid crystalline containing Cu （ Ⅱ ）, Zn（ Ⅱ ）, Li＋ , oxovanadyl metal ion.

关 键 词：超分子液晶 自组装 铵离子 金属离子配位 

分 类 号：O753.2[理学—晶体学]