Electron Momentum Spectroscopy of Ethanethiol Complete Valence Shell  

作　　者：Xin-xia Xue Mi Yan Fang Wu Xu Shan Ke-zun Xu Xiang-jun Chen 

机构地区：[1]Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei 230025, China

出　　处：《Chinese Journal of Chemical Physics》2008年第6期515-520,共6页化学物理学报（英文）

基　　金：ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.10734040） and the Foundation for Major Research Program of Education Department of Anhui Province （No.ZD2007002-1）.

摘　　要：The binding energy spectra and electron momentum distributions for the complete valence orbitals of ethanethiol were measured for the first time by binary （e, 2e） electron momentum spectroscopy employing non-coplanar symmetric kinematics at an impact energy of 1200 eV plus binding energy. The experimental results are generally consistent with the theoretical calculations using density functional theory and Hartree-Fock methods with various basis sets. A possible satellite line at 17.8 eV in binding energy spectrum was observed and studied by electron momentum spectroscopy.

关 键 词：ETHANETHIOL Electron momentum spectroscopy Valence orbital Satellite line Binding energy spectrum 

分 类 号：O561.3[理学—原子与分子物理] TQ658.91[理学—物理]