非均相回流技术制备开口ZnS空心微球  

Preparation of ZnS hollow microspheres with small open holes by heterogeneous-phase reflux technique

作　　者：王寅珏[1] 邵兵[1] 张文莉[1] 邵怿[1] 倪良[1] 

机构地区：[1]江苏大学化学化工学院,江苏镇江212013

出　　处：《现代化工》2008年第12期59-61,共3页Modern Chemical Industry

基　　金：国家自然科学基金项目(20773109);镇江市社会发展项目(SH2006067)

摘　　要：以部分互溶的水-乙醚液液平衡系统为反应介质,硫代乙酰胺和醋酸锌分别为硫源和锌源,通过非均相回流技术成功制备了开口硫化锌空心微球,并对所得样品进行了性能表征。开口硫化锌空心微球形貌规整,直径约为8μm,开口圆孔直径约为1.6μm,纯度高,具有立方晶相结构。Using the soluble-partly water-ether equilibrium system as the reaction medium, thioacetamide and zinc acetate as sulfur source and zinc source respectively, the ZnS hollow microspheres with small open holes are prepared by using the heterogeneous-phase reflux technique. The products are characterized also. The diameter of the microspheres is about 8 um, and the diameter of small open holes is about 1.6um , the purity is high and a pattern of cubic structure is exhibited.

关 键 词：硫化锌 空心微球 回流技术 

分 类 号：TQ132.41[化学工程—无机化工]