新型太阳能材料C_(60)Pt(dppp)配合物的合成及性能  

Synthesis and Property of Noval Solar Energy of C_(60)Pt(dppp)

作　　者：杨绳岩[1] 张娜[1] 吴振奕[1] 

机构地区：[1]厦门大学化学化工学院化学系,厦门361005

出　　处：《无机材料学报》2009年第1期18-22,共5页Journal of Inorganic Materials

基　　金：福建省自然科学基金(E0410001;E0110002)

摘　　要：以C60及双齿膦dppp为配体,在氮气氛下合成出C60Pt(dppp)配合物,采用质谱、元素分析、红外光谱、紫外可见光谱以及光电子能谱等手段对产物进行表征.同时研究了产物的光电性能及氧化还原性能.光伏效应研究结果表明:产物具有优良的光电转化性能,尤其是在BQ/H2Q介质电对中,光生电压最大达到371mV;当C60Pt(dppp)薄膜厚度为1μm时,光伏效应值最大.The fullerene complex C60 Pt （dppp） was prepared by reacting C60 with dppp in nitrogen atmosphere. The synthesized fullerene complex was characterized by means of Mass Spectrometry （ MS）, Elemental Analysis, FT-IR, UV-Vis and XPS. Besides these, the photoelectric properties and redox property of this complex were also studied. The results show that the greatest value of photovotaic potential is 371mV in the benzoquinone/hydroquinone redox couple, and the value of photovoltaic effects reach the maximum when the thickness of complex film is 1 μm. Based on the merits mensioned above, the complex has excellent photoelectric properties, therefore it has potential application in solar cells.

关 键 词：富勒烯 铂配合物 光电性能 

分 类 号：O641[理学—物理化学] O644[理学—化学]