Pt-Ru-W/C催化剂对乙醇电催化氧化研究  

Investigation of ethanol electro-oxidation on Pt-Ru-W/C catalyst

作　　者：王振波[1] 左朋建[1] 王广进[1] 王家钧[1] 尹鸽平[1] 

机构地区：[1]哈尔滨工业大学化工学院,黑龙江哈尔滨150001

出　　处：《电源技术》2009年第1期10-13,共4页Chinese Journal of Power Sources

基　　金：国家自然科学基金(20606007);教育部留学回国人员科研启动基金(2008);黑龙江省博士后科研启动资金(LBH-Q07044)资助项目

摘　　要：为了提高直接乙醇燃料电池阳极催化剂的催化活性,降低贵金属载量,采用热还原法制备了Pt-Ru-W/C催化剂,比较了Pt-Ru-W/C和相同前驱体用化学还原法制备的Pt-Ru/C催化剂对乙醇的电催化氧化行为;在0.5mol/L乙醇和0.5mol/L硫酸混合溶液中考核了上述催化剂对乙醇电催化氧化活性;通过X射线衍射光谱法(XRD)技术对催化剂的晶体结构进行了分析;结果表明:两种催化剂都具有Pt的面心立方晶格结构,晶格参数都小于Pt/C催化剂;计算表明Pt-Ru-W/C粒径较小,为6.5nm左右;Pt-Ru-W/C电化学活性比表面积小于Pt-Ru/C催化剂,但由于W的助催化作用使Pt-Ru-W/C对乙醇的电催化活性和抗乙醇中间产物毒化的能力高于Pt-Ru/C催化剂。In order to increase the activity of anodic catalysts and thus to lower noble metal loading in anodes for ethanol electrooxidation. Direct ethanol fuel cell anodic catalysts, Pt-Ru-W/C, was prepared by thermal reduction. The Pt-Ru/C catalyst prepared by chemical reduction of H2PtCl6 and RuCI3 as precursors was used to compare. Their performances of catalysts were tested through cyclic voltammetric curves and chronoamperometric curves in a solution of 0.5 mol/L CH3CH2OH and 0.5 mol/L H2SO4. The particle sizes and their structures of the catalysts were determined by means of X-ray diffraction （XRD）. XRD analysis shows that both catalysts exhibit face-centered cubic structures and have smaller lattice parameters than Pt-alone catalyst. The particle size of Pt-Ru-W/C catalyst is relatively small, about 6.5 rim. The electrochemically active specific area of Pt-Ru-W/C catalyst is less 20 m^2/g than that of the Pt-Ru/C. But, the catalytic activity of the Pt-Ru-W/C catalyst for ethanol electrooxidation is better than that of the Pt-Ru/C due to the promoting function of W. Its tolerance performance to CO from intermediates of ethanol electrooxidation is better than that of the Pt-Ru/C.

关 键 词：直接乙醇燃料电池 Pt-Ru—W C催化剂 Pt—Ru/C催化剂:乙醇电氧化 

分 类 号：TM911.4[电气工程—电力电子与电力传动]