N-乙酸邻菲啉的合成及其锰盐配合物的研究  

Synthesis and studies on N monoacetate phenanthroline and its complexes of different manganous salts

作　　者：郭琦[1] 马娴贤[2] 姚卡玲[2] 

机构地区：[1]江苏教育学院化学系 [2]兰州大学化学系

出　　处：《西北师范大学学报（自然科学版）》1998年第2期57-61,共5页Journal of Northwest Normal University(Natural Science)

基　　金：甘肃省教委科研资助

摘　　要：合成了Ｎ一羧乙基邻菲口罗啉，制备了其与不同锰盐（硫酸锰和氯化锰）形成的配合物，通过化学方法和元素分析结果确定了配合物的组成，并测定了配合物的摩尔电导、磁化率、溶解性．通过红外光谱、紫外光谱、热谱及Ｘ射线粉末衍射对配合物的结构进行了研究．N monoacetate phenanthroline and its complexes of different manganous salts(sulfate and chloride) are prepared.The compositions and properties of N monoacetate phenanthroline and two complexes of manganous salts have been determined and characterized by chemical and elemental analysis,infrared spectra,ultraviolet spectra,molar conductance,magnetic susceptibilities,thermogravimetric(TG) and differential thermal analysis(DTA) and X ray powder diffraction,which have differential crystal structure.The solublities of complexes in different solvents has been investigated also.

关 键 词：邻菲罗啉 乙酸邻菲罗啉 锰盐 配合物 合成 

分 类 号：O657.3[理学—分析化学] O614.711[理学—化学]