计算机Monte Carlo法模拟自由基交联共聚网络结构的增长  

THE MONTE CARLO SIMULATION OF THE EVOLUTION OF NETWORK STRUCTURE OF RADICAL CROSS-LINKING COPOLYMERIZATION BY COMPUTER

作　　者：陈天红[1] 冯鸣华[1] 左榘[2] 何炳林[2] 

机构地区：[1]南开大学化学系,天津300071 [2]南开大学吸附分离功能高分子材料国家重点实验室,化学系天津300071

出　　处：《离子交换与吸附》1998年第2期139-143,共5页Ion Exchange and Adsorption

基　　金：天津市自然科学基金

摘　　要：本文成功地用MonteCarlo方法模拟了以画面方式表示的苯乙烯-二乙烯苯交联共聚反应中大分子链增长、支化及交联的进化情况，并给出了相应的转化率，以定量模型的方式描述了该类反应。The paper succeeded in the Monte Carlo Simulation on growing, branching and cross-linking of the polymer chains for the copolymerization of styrene with divinylbenzene in the manners of picture. In addition, the corresponding conversions were also given. This gelation reaction was described by means of quantitative model.

关 键 词：苯乙烯 二乙烯苯 共聚 凝胶化反应 交联共聚 

分 类 号：O631.5[理学—高分子化学] TQ316.342[理学—化学]