用CRDS技术研究分子光谱和气相反应动力学  

Measurement of Molecular Spectroscopy and Kinetics in Gas Phase by Means of CRDS Technique

作　　者：黄建华[1] 杨何平[1] 詹际平[1] 韩克利[1] 何国钟[1] 楼南泉[1] 

机构地区：[1]中国科学院大连化学物理研究所分子反应动力学国家重点实验室

出　　处：《Chinese Journal of Chemical Physics》1998年第2期119-123,共5页化学物理学报（英文）

摘　　要：介绍了用ＣＲＤＳ技术研究分子光谱和气相反应动力学，把ＣＲＤＳ光谱技术应用于Ｉ２（Ｂ３∏（０＋ｕ）←Ｘ１∑＋ｇ）的光谱，利用ＣＲＤＳ方法测量了反射镜的反射率，Ｉ２的蒸汽压为０．１Ｐａ，脉冲激光能量为０．１ｍＪ。Recent years a new technique,Cavity-Ring-Down spectroscopy(CRDS),has been developed quickly,which allows an increase of several orders of magnitude in sensitivity over existing techniques for the wide spectral region accessible with tunable pulsed lasers.The principle of operation is based,not on the measurement of the absorbed signal strength for a given sample path,but of the time rate of decay of a pulse of light trapped in a high reflectance opticalc avity.Due to its many advantages,it has become a powerful tool for spectroscopic measurement of weak transitions.This sensitive technique was extended for kinetic measurement for the first time by M.C.Lin et al..They used this new technique successfully to measure the absolute values of rate constants for several C 6H 5 reactions.The application of CRDS technique to molecular spectroscopy and kinetics in gas phase is described briefly.A portion of the I 2(B 3∏(0 + u)←X 1∑ + g)continuous spectrum has been recorded by means of CRDS technique for the first time.The reflectivity of the mirrors has been measured by means of CRDS technique.The vapor pressure of I 2 was 0.1Pa and pulsed dye laser energy was 0.1mJ.

关 键 词：CRDS 分子光谱 动力学 碘分子 气相反应动力学 

分 类 号：O613.44[理学—无机化学] O643.131[理学—化学]