基于原位反应合成的一个锌的配位聚合物(英文)  

A Photoluminescent Zinc(Ⅱ) Metal-organic Framework Constructed from a in-situ Synthesized Tetrazole Ligand

作　　者：黄荣谊[1] 朱坤[1] 陈宏[1] 刘光祥[1] 任小明[1] 

机构地区：[1]安庆师范学院化学化工学院,功能配合物安徽省重点实验室,安庆246003

出　　处：《无机化学学报》2009年第1期162-165,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.20371002,20771006)

摘　　要：A coordination polymer of Zn(IBT)2 (2) (HIBT=5-(4-((1H-imidazol-1-yl)methyl)phenyl)-2H-tetrazole) has been prepared by hydrothermal method and characterized by IR spectroscopy,elemental analysis and single-crystal X-ray diffraction structure analysis. Compound 2 has one-dimensional (1D) hinged chain structure and displays strong photoluminescent emission at room temperature.A coordination polymer of Zn（IBT）2 （2） （HIBT=5-（4-（（1H-imidazol-1-yl）methyl）phenyl）-2H-tetrazole） has been prepared by hydrothermal method and characterized by IR spectroscopy,elemental analysis and single-crystal X-ray diffraction structure analysis. Compound 2 has one-dimensional （1D） hinged chain structure and displays strong photoluminescent emission at room temperature.

关 键 词：锌的配合物 原位反应 四氮唑配体 荧光性质 

分 类 号：O614.241[理学—无机化学]