改性β分子筛催化苯与苯酐合成蒽醌的研究  

Study on synthesis anthraquinone from phthalic anhydride and benzene over modified β zeolite catalyst

作　　者：贾振[1] 姜翠玉[1] 宋林花[1] 徐永强[1] 

机构地区：[1]中国石油大学(华东)化学化工学院,山东青岛266555

出　　处：《应用化工》2009年第1期99-101,共3页Applied Chemical Industry

摘　　要：对不同改性β分子筛催化剂催化合成蒽醌进行了研究。结果表明,Hβ改性催化剂对催化合成蒽醌效果较好,苯酐转化率达33.6%;固体超强酸对β分子筛的改性SO42-/ZrO2优于SO42-/Fe2O3;稀土元素铈的氧化物改性使蒽醌的选择性有较大提高,可达98.2%。Anthraquinone was synthesised using different modified β zeolites catalysts. The result showed that Hβ modified catalyst had better catalytic efficiency for synthesizing anthraquinone, and the conve sion of anthraquinone was about 33.6% ;The effect of β zeolite modified with SO4^2-/ZrO2 was better than SO4^2-/Fe2O3 ;The selectivity of anthraquinone has improved greatly using β zeolite modified with cerium oxide, and the selectivity has reached 98.2%.

关 键 词：Β分子筛 蒽醌 苯酐法 改性 

分 类 号：TQ032.41[化学工程]