氮杂杯[6]芳烃迭氮化衍生物的合成与表征  

Synthesis and characterization of aza-bridged calix[6]arene azides-derivative

作　　者：王晶[1] 曹端林[1] 胡志勇[1] 张文艳[1] 

机构地区：[1]中北大学化工与环境学院,山西太原030051

出　　处：《应用化工》2009年第1期114-115,123,共3页Applied Chemical Industry

摘　　要：以氮杂杯[6]芳烃和迭氮化钠为原料，四氢呋喃为溶剂，在为40～45℃合成了氮杂杯[6]芳烃迭氮化衍生物，通过薄层色谱分析法、红外光谱分析法和核磁共振氢谱法对产物进行了表征，证实其为目标产物，从而验证了合成路线的可行性。In this paper, ultimate production aza-bridged calix[ 6 ] arene azides-derivative was synthesized from aza-bridged calix[6] arene and sodium azide in the experiment,THF as solvent,at 40 - 45 ℃. The product is characterized through TLC, FT-IR and ^1H NMR. It is proved that it is the target product, conse- quently synthesis path is feasible.

关 键 词：芳烃 迭氮化衍生物 表征 

分 类 号：O69[理学—化学]