新型二茂铁异噁唑啉衍生物的合成及其电化学性能  

Synthesis of Novel Ferrocenyl Isoxazoline Derivatives and Their Electrochemical Performance

作　　者：郑彩云[1,2] 吴建伟[1] 何心伟[1] 张传菊[1] 樊陈莉[1] 商永嘉[1] 

机构地区：[1]安徽师范大学化学与材料科学学院安徽省分子固体重点实验室,安徽芜湖241000 [2]番禺职业技术学院,广东广州511483

出　　处：《合成化学》2009年第1期91-94,共4页Chinese Journal of Synthetic Chemistry

基　　金：安徽省教育厅自然科学基金项目资助(2006kj117B,KJ2008A064)

摘　　要：二茂铁基α,β-不饱和烯酮与腈氧化物发生1,3-偶极环加成反应合成了7个3-取代苯基-4-苯基-5-二茂铁甲酰基异噁唑啉(4a^4 g),产率中等,其结构经1H NMR,IR和MS表征。通过循环伏安曲线研究了4的电化学性能,结果表明,苯环上的取代基对4的氧化还原电位有一定影响。Seven novel ferrocenyl isoxazoline derivatives, 3-substituted phenyl-4-phenyl-5-ferrocenyl- formyl-isoxazolines （4a - 4g）, were synthesized by 1,3-dipolar cycloaddition between ferrocenyl α ,β- unsaturated ketene and nitrile oxides in moderate yields. The structures were characterized by ^1H NMR, IR and MS. The electrochemical performance of 4 was investigated by cyclic voltammetry curve. The results showed that the substituted group on benzene had some effects on oxidation-reduction potential of 4.

关 键 词：二茂铁 异噁唑啉 Α Β-不饱和酮 1 3-偶极环加成 电化学行为 

分 类 号：O627.8[理学—有机化学]