基于模板法的纳米结构二氧化硅仿生合成研究进展  

The research for the template-based biomietic synthesis of nano-structured silica

作　　者：李小青[1] 袁建军[1] 程时远[1] 

机构地区：[1]湖北大学材料科学与工程学院,武汉430062

出　　处：《胶体与聚合物》2009年第1期41-44,共4页Chinese Journal of Colloid & Polymer

基　　金：国家自然科学基金(50703006);湖北省教育厅重大项目(Z200710001);武汉市晨光计划(200750731275)

摘　　要：与传统化学合成方法相比,自然界中二氧化硅的形成反应(biosilicification)无污染、能耗低、在环境条件下就可快速完成,并且具有在纳米尺度下对所形成二氧化硅的结构和形态进行精确控制的能力。因此纳米SiO2的仿生合成,尤其是模板条件下的仿生合成已经成为人们最近的研究热点。本文主要介绍了采用分子模板、纳米纤维模板、自组装共聚物聚集体模板、微凝胶模板、无机纳米材料模板和微加工技术等,介绍仿生合成纳米SiO2的研究进展。Compared to conventional chemical approaches for silica formation, biosilicification in Nature often involves non-pollution, low-energy consumption and rapid mineralized reaction under ambient conditions. In addition, the nanostructure and morphology could be precisely controlled in organism. Therefore, the biomimetic synthesis of nano-structured silica, especially template-mediated silica deposition at ambient conditions has been one of important research field in materials sciences. In this paper, we have reviewed the recent progress for bio-inspired silica formation of nanostructure silicas templated by designed macromoleclues, nanofibers, self-assembled block copolymer aggregates, polymeric microgel, inorganic nanoparticles and micro-processing technology.

关 键 词：仿生SiO2 模板 形态控制 

分 类 号：TQ127.2[化学工程—无机化工] TB321[一般工业技术—材料科学与工程]