炭化树脂负载杂多酸催化剂的制备和表征  

SYNTHESIS AND CHARACTERIZATION OF HETEROPOLY ACID CATALYST SUPPORTED ON CARBONIZED RESIN

作　　者：高峰[1] 孙经武[1] 钟顺和[2] 

机构地区：[1]天津大学应用化学系 [2]天津大学化学工程系

出　　处：《催化学报》1998年第2期187-190,共4页

摘　　要：炭化树脂负载杂多酸催化剂的制备和表征高峰孙经武（天津大学应用化学系，天津３０００７２）钟顺和（天津大学化学工程系，天津３０００７２）关键词炭化树脂，磷钨酸，负载型催化剂，烷基化反应分类号Ｏ６４３杂多酸作为一种新型的多功能催化剂正日益受到人们的关注［...Using polystyrene type macroporous cation-exchange resin D72 as the precursor, the high intensity globular carbonized resin was manufactured by the method of high temperature carbonization and water vapor activation. Carbonized resin supported 12-phosphotungstic acid (HPW) catalyst was synthesized through dipping process. Their composition, structure and physico-chemical character were detected by BET, IR, SEM, XRD and solvent dissolve methods. The catalytic activity was checked by using synthesis of alkylphenol as the mold reaction. It has been found that carbonized resin is a kind of carrier with stable structure, homogeneous pore diameter, high specific surface area and plenty of oxygen-containing active sites on the surface. HPW can be dispersed in monomolecular layer and linked with oxygen-containing active sites on the surface of the carrier. Carbonized resin supported HPW catalyst is a kind of solid acid catalyst that has high intensity, stable composition, satisfactory activity and high selectivity.

关 键 词：炭化树脂 磷钨酸 负载型 催化剂 烷基化 制备 

分 类 号：TQ426.64[化学工程]