富勒烯(C_(60/70))-丙烯酸的自由基共聚  

Free Radical Copolymerization of Fullerenes(C 60/70 ) with Acrylic Acid

作　　者：官文超[1] 段标[1] 余俊 

机构地区：[1]华中理工大学化学系机械科学与工程学院

出　　处：《高等学校化学学报》1998年第3期492-493,共2页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：富勒烯及其衍生物在超导、光电、磁学等领域展现出奇特性能［１］，富勒烯的化学修饰成为化学工作者们关注的热点之一，而其中合成含富勒烯的新型聚合物是一个非常重要的方面．Ｌｏｙ和Ａｓｓｉｎｋ［２］报道过对二甲苯与Ｃ６０的共聚物；Ｈｉｒｓｃｈ和Ｐａｔｉｌ［３］...C 60/70 acrylic acid water soluble copolymer, whose average molecular weight is 2 000 , was synthesized by means of typical free radical copolymerization method. C 60/70 (85% C 60 , 14%C 70 , 1% high fullerenes) mixture of 45 mg and 2.5 mL acrylic acid were dissolved in 15 mL toluene. The polymerization was initiated by 30 mg AIBN at 70 ℃ under the protection of N 2 for 13￣15 h, yielding a red brown precipitate. The pured copolymer which is soluble in water has significantly different spectroscopic properties from C 60/70 .

关 键 词：富勒烯 自由基共聚 共聚物 碳60 碳70 丙烯酸 

分 类 号：O632.1[理学—高分子化学]