铜(Ⅱ)-α,α'-联吡啶-二氧四胺大环三元体系的热化学性质  

Study of Thermochemical Properties of Cu (Ⅱ)-α,α'-bipyridyl-macrocyclic Dioxotetraamine Ternary Systems

作　　者：周志芬[1] 林华宽[1] 李苏琦[1] 朱守荣[1] 陈荣悌[1] 

机构地区：[1]南开大学化学系,天津300071

出　　处：《物理化学学报》1998年第4期343-348,共6页Acta Physico-Chimica Sinica

基　　金：国家自然科学基金

摘　　要：Thermal effects of coordination reaction of Cu(Ⅱ )-α,α’-bipyridyl-macrocyclic diox-otetraaming ternary complex compounds have been determined in aqueous solution at 25.0±0.1℃and I=0.1 mol.dm-3 KNO3 by means of model RD-1 automatic conduction calorimeter. Linearthermodynamic function relationships have been found to exist in this ternary system. Ther-modynamic properties of Cu(Ⅱ)biPy/phen-HRTADO ternary systems have been compared anddiscussed. The effects of substituents and stacking of aromatic ring to the thermodynamic prop-erties Cu(Ⅱ)-bipy/phen-HRTADO ternary systems also have been discussed.Thermal effects of coordination reaction of Cu(Ⅱ )-α,α'-bipyridyl-macrocyclic diox-otetraaming ternary complex compounds have been determined in aqueous solution at 25.0±0.1℃and I=0.1 mol.dm-3 KNO3 by means of model RD-1 automatic conduction calorimeter. Linearthermodynamic function relationships have been found to exist in this ternary system. Ther-modynamic properties of Cu(Ⅱ)biPy/phen-HRTADO ternary systems have been compared anddiscussed. The effects of substituents and stacking of aromatic ring to the thermodynamic prop-erties Cu(Ⅱ)-bipy/phen-HRTADO ternary systems also have been discussed.

关 键 词：铜 联吡啶 二氧四胺大环 大环 三元 配合物 

分 类 号：O614.121[理学—无机化学]