Quenching Study on Iron Impurity in Eu^(2+), Dy^(3+) Doped Strontium Aluminate Phosphor Prepared by Nano-Coating Process  

作　　者：杨雪峰 宁桂玲 刘杰 潘文 林源 

机构地区：[1]State Key Laboratory of Fine Chemicals and School of Chemical Engineering, Dalian University of Technology

出　　处：《Journal of Rare Earths》2007年第S1期326-329,共4页稀土学报（英文版）

基　　金：the National Natural Science Foundation of China (20376009)

摘　　要：A series of long afterglow phosphors, Eu2+, Dy3+, with different iron content were prepared by nano-coating process. The resulted precursors were characterized by Transmission Electron Microscope (TEM), which suggested that the precursor particles had nanometer size distribution. The optical quenching of iron impurity on the phosphor powders were investigated by X-Ray powder Diffraction (XRD) and photoluminescence methods. The XRD indicates that a pure monoclinic SrAl2O4∶Eu2+, Dy3+ was formed at 1200 ℃ and iron impurity up to 296.36×10-4% had no effect on the SrAl2O4∶Eu2+, Dy3+ phase structure. However, the luminescence intensity were strongly dependent on the trace iron impurity, which might be explained that iron displace the aluminium and form Fe-O bond, which competed energy with Eu2+ and transfer red them to infrared sites.A series of long afterglow phosphors, Eu2+, Dy3+, with different iron content were prepared by nano-coating process. The resulted precursors were characterized by Transmission Electron Microscope (TEM), which suggested that the precursor particles had nanometer size distribution. The optical quenching of iron impurity on the phosphor powders were investigated by X-Ray powder Diffraction (XRD) and photoluminescence methods. The XRD indicates that a pure monoclinic SrAl2O4∶Eu2+, Dy3+ was formed at 1200 ℃ and iron impurity up to 296.36×10-4% had no effect on the SrAl2O4∶Eu2+, Dy3+ phase structure. However, the luminescence intensity were strongly dependent on the trace iron impurity, which might be explained that iron displace the aluminium and form Fe-O bond, which competed energy with Eu2+ and transfer red them to infrared sites.

关 键 词：long afterglow phosphor SrAl_2O_4∶Eu^(2+)  Dy^(3+) iron impurity QUENCHING rare earths 

分 类 号：O614.3[理学—无机化学]