A new efficient route for the synthesis of 4,4′,6,6′-tetra-(azido)azo-1,3,5-triazine  

作　　者：Xiao Tong Li Sheng Hua Li Si Ping Pang Yong Zhong Yu Yun Jun Luo 

机构地区：[1]School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China [2]School of Life Science & Technology, Beijing Institute of Technology, Beijing 100081, China

出　　处：《Chinese Chemical Letters》2007年第9期1037-1039,共3页中国化学快报（英文版）

摘　　要：A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize TAHT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize TAHT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.

关 键 词：High-nitrogen compounds AZIDE TRIAZINE Synthesis 

分 类 号：O626[理学—有机化学]