Recent progress in lantha-nide-catalyzed organic reactions in protic media  

作　　者：LUO Sanzhong ZHANG Baolian XIAN Ming Adam Janczuk XIE Wenhua CHENG Jinpei Peng George Wang 

机构地区：[1]Department of Chemistry,Nankai University,Tianjin 300071,China [2]Department of Chemistry,Wayne State University,Detroit MI 48202-3489,USA

出　　处：《Chinese Science Bulletin》2001年第20期1673-1681,共9页

基　　金：This work was supported by the National Natural Science Foundation of China (Grant No. 29928004).

摘　　要：Lanthanide triflates are stable in water. It is possible for lanthanides to undergo many organic reactions in environmentally friendly solvents. This makes lanthanides very promising in the field of green chemistry. This review describes the recent development of the lanthanide-catalyzed organic reactions in protic solvents. Those reac-tions include Diels-Alder, Aldol, Allylation, acetalization, pericyclization, radical reactions as well as some newly-developed lanthnides-based catalysts.Lanthanide triflates are stable in water. It is possible for lanthanides to undergo many organic reactions in environmentally friendly solvents. This makes lanthanides very promising in the field of green chemistry. This review describes the recent development of the lanthanidecatalyzed organic reactions in protic solvents. Those reactions include Diels-Alder, Aldol, Allylation, acetalization, pericyclization, radical reactions as well as some newlydeveloped lanthnidesbased catalysts.

关 键 词：green CHEMISTRY LANTHANIDE TRIFLATE AQUEOUS media organic syntheses. 

分 类 号：O621.25[理学—有机化学]