Determination of Non-Rare Earth Impurities in High Purity Lanthanum Oxide by Inductively Coupled Plasma Atomic Emission Spectrometry after HPLC Separation Using P507 Resin  

作　　者：江祖成 胡斌 帅琴 秦永超 王雷 

出　　处：《Journal of Rare Earths》2001年第4期299-303,共5页稀土学报（英文版）

基　　金：ProjectsupportedbytheNationalScienceFoundationofChina ( 2 9875 0 2 2 ) ;WuhanMunicipalScience&TechnologyCommis sion

摘　　要：A new method for the determination of trace non-rare earth elements (NREEs) impurities in high-purity lanthanum oxide by HPLC combined with ICP-AES is proposed. The chromatographic retention behaviors of matrix (La) and NREEs were studied using 2-ethylhexyl hydrogen 2-ethylhexyl phosphonate (P507) chelating resin as the stationary phase and dilute nitric acid as the mobile phase. It is found that the use of pH 1.7 nitric acid enables effective elution of NREEs from HPLC column, but the lanthanum remains on the column. The experimental results show that a favorable separation between matrix lanthanum and NREEs can be obtained within 15 min. The method proposed is applied to the determination of 8 NREEs impurities in high-purity La2O3. The recoveries of 8 NREEs are in the range of 90 % similar to 110 %.A new method for the determination of trace non-rare earth elements (NREEs) impurities in high-purity lanthanum oxide by HPLC combined with ICP-AES is proposed. The chromatographic retention behaviors of matrix (La) and NREEs were studied using 2-ethylhexyl hydrogen 2-ethylhexyl phosphonate (P507) chelating resin as the stationary phase and dilute nitric acid as the mobile phase. It is found that the use of pH 1.7 nitric acid enables effective elution of NREEs from HPLC column, but the lanthanum remains on the column. The experimental results show that a favorable separation between matrix lanthanum and NREEs can be obtained within 15 min. The method proposed is applied to the determination of 8 NREEs impurities in high-purity La2O3. The recoveries of 8 NREEs are in the range of 90 % similar to 110 %.

关 键 词：rare earths HPLC 2-ethylhexyl hydrogen 2-ethylhexylphosphonate (P507) ICP-AES high-purity lanthanum oxide non rare earth impurities 

分 类 号：O657.31[理学—分析化学]