A Chiral Phosphorous Derivatizing Agent for the Determination of the Enantiomeric Excess of Chiral Alcohols, Amines by ^(31)P NMR  

作　　者：Kang Ying LI Zheng Hong ZHOU Chi Hung YEUNG Chu Chi TANG 

机构地区：[1]State Key Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin 300071 [2]Laboratory of Chiral Technology and Department of Applied Biology and Chemical Technology,The Hong Kong Polytcchnic University,Hong Kong

出　　处：《Chinese Chemical Letters》2001年第10期907-908,共2页中国化学快报(英文版)

基　　金：We are very grateful for the financial support of the National Natural Science Foundation of China (No.29872016) and the Hong Kong Polytechnic University ASD Fund.

摘　　要：A chiral phosphorous derivatizing agent prepared from PCl3 and (S)-BINOL was described. It is used to determine the enantiomeric excess of chiral alcohols and amines by 31P NMR.A chiral phosphorous derivatizing agent prepared from PCl3 and (S)-BINOL was described. It is used to determine the enantiomeric excess of chiral alcohols and amines by 31P NMR.

关 键 词：Chiral phosphorous DERIVATION chiral alcohols chiral amines enantiomeric excess asymmetric induction. 

分 类 号：O623[理学—有机化学]